KEGG   REACTION: R06625
Entry
R06625                      Reaction                               
Name
malonyl-CoA:malonyl-CoA malonyltransferase (3,5-dihydroxyphenylacetyl-CoA-forming)
Definition
4 Malonyl-CoA <=> 3,5-Dihydroxyphenylacetyl-CoA + 3 CoA + 4 CO2 + H2O
Equation
4 C00083 <=> C12324 + 3 C00010 + 4 C00011 + C00001
Comment
typeIII polyketide synthase, DpgA
dehydratase/isomerase, DpgB+DpgD
multi-step reaction
Reaction class
RC00004  C00010_C00083
RC02933  C00083_C12324
Enzyme
Pathway
rn01055  Biosynthesis of vancomycin group antibiotics
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.3  Acyltransferases
   2.3.1  Transferring groups other than aminoacyl groups
    2.3.1.246
     R06625  4 Malonyl-CoA <=> 3,5-Dihydroxyphenylacetyl-CoA + 3 CoA + 4 CO2 + H2O
Orthology
K16424  3,5-dihydroxyphenylacetyl-CoA synthase [EC:2.3.1.246]
K16425  isomerase DpgB
K16426  dehydration protein DpgD
Other DBs
RHEA: 44747

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